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Hartree equation : ウィキペディア英語版
Hartree equation

In 1927, a year after the publication of the Schrödinger equation, Hartree formulated what are now known as
the Hartree equations for atoms, using the concept of ''self-consistency'' that Lindsay had introduced in his study of many electron systems in the context of Bohr theory. Hartree assumed that the nucleus together with the electrons formed a spherically symmetric field. The charge distribution of each electron was the solution of the Schrödinger equation for an electron in a potential v(r) , derived from the field. Self-consistency required that the final field, computed from the solutions was self-consistent with the initial field and he called his method the self-consistent field method.
In order to solve the equation of an electron in a spherical potential, Hartree first introduced atomic units to eliminate physical constants. Then he converted the Laplacian from Cartesian to spherical coordinates to show that the solution was a product of a radial function P(r)/r and a spherical harmonic with an angular quantum number \ell, namely \psi=(1/r)P(r)S_\ell(\theta,\phi). The equation for the radial function was

:d^2P(r)/dr^2 + (- \ell(\ell+1)/r^2 )P(r)=0.
In mathematics, the Hartree equation, named after Douglas Hartree, is
:i\,\partial_tu + \nabla^2 u= V(u)u
in \mathbb^
where
:V(u)= \pm |x|^
* |u|^2
and
: 0 < n < d
The non-linear Schrödinger equation is in some sense a limiting case.
==External links==

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抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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